The simplest process is to heat lithium in the presence of chlorine:
Li + Cl -> LiCl
or to make it a bit more complex, create lithium oxide and free an oxygen atom by burning two atoms of lithium in oxygen:
2(Li) + O2 -> Li2O + O
and then dissolving the lithium oxide in hydrochloric acid:
Li2O + 2(HCl) -> 2(LiCl) + H20
yielding 2 molecules of lithium chloride and a molecule of water.
Encyclopedia Britannica, 11th ed., vol. 16, pg. 785.
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