CH4(g) + O2(g)-->CO2(g) + H2O(g)
When you balance out an equation you get the same amount of each element on both sides of the equation.
In this problem we have 1 carbon on both sides, 4 hydrogen on the right and 2 on the left, and 2 oxygens on the left and 3 on the right side.
We need to balance out the hydrogens therefore we add a two to make it equal:
CH4(g) + O2(g)-->CO2(g) + 2H2O(g)
Now we have 1 carbon, and 4 hydrogen on both sides but 2 oxygen on the left and 4 on the right, so we have to balance that out.
We do so by putting in another 2:
CH4(g) + 2O2(g)-->CO2(g) + 2H2O(g)
Now we have 1 carbon, 4 oxygen, and 4 hydrogen.
It is now balanced.
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